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4.0 Corrosion and Cathodic Protection

 

(488KB) Predicting the Performance of Cathodic Protection Systems with Large Scale Interference - Robert Adey, John Baynham, Tom Curtin

Understanding the interactions between cathodic protection systems is becoming more complex particularly in the marine and offshore industry. The search for oil and gas in deeper waters and remote environments has resulted in engineering designs with many components on the sea bed as well as at the sea surface.

 

(1,387KB) Predicting Corrosion Related Signatures - Robert Adey and J.M.W. Baynham.

Computer simulation has been widely used to predict the corrosion related electric and electromagnetic signatures of naval vessels. The modelling strategy has varied from simple dipole type models to detailed boundary element models of the vessel and its environment.

 

(492KB) Experimental Measurement and Computer Simulation of Galvanic Corrosion of Magnesium Coupled to Steel

Jimmy X. Jia,Guangling Song and Andrej Atrens, 2007

DOI: 10.1002/adem.200600206

 

(514KB) Influence of geometry on galvanic corrosion of AZ91D coupled to steel

Jimmy X. Jia, Guangling Song, Andrej Atrens, 2006

DOI: 10.1016/j.corsci.2005.08.013

 

(15.9MB) Power Point Presentation - Validation and Optimising CP System Designs Top

E. Santana-Diaz

 

(1.06MB) A Complete Underwater Electric and Magnetic Signature Scenario Using Computational Modelling .Top
E. Santana-Diaz, R. Tims.  Marelec, April 2006

 

Computer modeling has been extensively used to predict the performance of Cathodic Protection systems, associated electric and magnetic signatures, and Degaussing systems.  This paper shows a complete Underwater Electric and Magnetic Signature scenario by combining the CRM in the water, the Hull Structure Magnetic Field, and the Magnetic Field from the Earth's Field Effect left over after Degaussing (DG ON), into one comprehensive Underwater Magnetic Signature. New approaches and computational tools, such as boundary elements and optimization techniques, will be used together to generate the complete scenario.

 

(504KB) Simulation of galvanic corrosion of magnesium coupled to a steel fastener in NaCl solution

J. X. Jia, A. Atrens, G. Song and T. H. Muster, 2005

DOI: 10.1002/maco.200403855

 

 

(1.06MB) Predicting the Coating Condition on Ships Using ICCP System Data.Top
E. Santana-Diaz, R. Adey.

 

 

(409KB) Evaluation of the BEASY program using linear and piecewise linear approaches for the boundary conditionsTop

J X Jia, A Atrens, D St John, J Baynham, G Chandler    Materials and Corrosion 2004, 55, No 11 pp 845-852

 

The boundary element method (BEM) was used to study galvanic corrosion using linear and logarithmic boundary conditions.  The linear boundary condition was implemented by using the linear approach and the piecewise linear approach.  The logarithmic boundary condition was implelement by the piecewise linear approach.  The calculated potential and current density distribution were compared with the prior analytical results. 

 

(1.43 Mb) Boundary Element Method Predictions of the Influence of the Electrolyte on the Galvanic Corrosion of AZ91D Coupled to SteelTop

J X Jia, A Atrens, G Song

 

This research investigated the galvanic corrosion of the magnesium alloy AZ91D coupled to steel. The galvanic current distribution was measured in 5% NaCl solution, corrosive water and an auto coolant. The experimental measurements were compared with predictions from a Boundary Element Method (BEM) model. The boundary condition, required as an input into the BEM model, needs to be a polarization curve that accurately reflects the corrosion process. Provided that the polarization curve does reflect steady state, the BEM model is expected to be able to reflect steady state galvanic corrosion.

 

(4.54Mb) Predicting the Effectiveness of Corrosion Control Measures Using Computer SimulationTop

R A Adey, E Santana Diaz 

Maritime Corrosion Conference, July 2004

 

(173KB) Simulating the Transient Response of ICCP Control Systems Top

JMW Baynham, R A Adey    Marelec, March 2004

The simulation of passive and active CP systems has over the years become a straightforward matter so that it is regularly performed to aid design and to assist understanding of system behaviour. Such numerical simulation takes into account the highly non-linear effects which take place during corrosion. This paper describes the application of CP simulation to modelling the dynamics of the complete ICCP system, including controllers, generators, anodes and reference cells.

 

(4.54Mb) Computer Simulation Of The Interference Between A Ship And Docks Cathodic Protection Systems Top

R A Adey, E Santana Diaz   

NACE Corrosion Conference, India, December 2003

 

Paint and impressed current cathodic protection (ICCP) systems are used to control corrosion on many different types of structures. Since cathodic protection (CP) systems were first applied, engineers have used experience and intensive monitoring to optimise their design to prevent corrosion. Numerical methods and in particular Boundary Elements Methods (BEM) have been widely used in the cathodic protection field to simulate the performance of the CP system and to predict the associated electric and magnetic fields.

 

(4.54Mb) Predictive Modelling of Corrosion and Cathodic Protection Systems Top

R A Adey, E Santana Diaz   

Tri-Service Corrosion Conference, USA, November 2003

Computer based modeling tools have developed in recent years to the stage where they are routinely used to assess the performance of corrosion control measures for naval ships and boats and critical parts of the infrastructure. They are also used to predict the important associated electric and magnetic fields induced by the corrosion related currents. Computer modeling enables the designer to build a virtual prototype of the ship or structure and predict how the corrosion control measures will perform over under various operational conditions.

 

(254KB) A combined design methodology for impressed current cathodic protection systems Top
V.G. DeGiorgi, E.D. Thomas II, K.E. Lucas, A. Kee

The corrosion prevention capability of shipboard impressed current cathodic protection systems are effected by the geometry of the ship hull, conductivity of the surrounding water, material polarization response and any material interactions. Changes in system configuration and service environment from those used in design analysis require the capability to analyze system performance under varied circumstances. While individually limited, experimental scale modeling and computational boundary element modeling techniques can be used in concert to design a robust system and to provide a means for quick analysis of system and environmental changes.

 

(189KB) Coating integrity effects on impressed current cathodic protection system parameters Top
V.G. DeGiorgi, C.P. Hamilton

A computational study of the changes in electrical current requirements due to damage to the corrosion preventative coating on the propellers of a U. S. Navy ship is performed. Coating damage is modeled using effective coating efficiency. The boundary element model used has been previously validated by comparison with physical scale modeling experimental results. Trends for higher current demand and lower potential at key locations with increasing levels of damage are presented.

 

(175KB) Influence of Seawater Composition on Corrosion Prevention System Parameters Top
V. G. DeGiorgi

Cathodic protection systems, such as those designed for ships, utilize material electrochemical properties to minimize corrosion damage. The extent of material interaction in the corrosion process is partially dependent on the resistivity of the surrounding medium. A medium with low resistivity, such as seawater, provides a greater degree of electrical connectivity than a medium of higher resistivity.

 

(347KB) Boundary Element Evaluation of ICCP Systems Under Simulated Service Conditions Top
V.G. DeGiorgi, K.E. Lucas, E.D. Thomas II, M.J. Shimko

The purpose of this work was to evaluate multiple material surface ship models and compare results, when possible, with scale model experimental results.

 

(399KB) Characterization accuracy in modeling of corrosion systems Top
V.G. DeGiorgi, A. Kee, E.D. Thomas

Boundary element techniques are well suited for the solution of LaPlace’s equation in semi-infinite and infinite volumes. As in any computer modeling, issues must be addressed in the early stages of the analysis for the finished work to be an accurate evaluation of the system. The goal of the analysis must be clearly defined; preliminary and trend analyses often require less mesh refinement than detailed system evaluations. The work presented is a portion of a detailed evaluation of the impressed current cathodic protection system of an U S Navy CG class surface ship.

 

(488KB) Computer Simulation as an aid to CP System Design and Interference Prediction Top
Robert Adey, John Baynham

Cathodic protection (CP) systems are commonly designed by estimating the overall current demand and then developing an anode configuration sufficient to protect the structure. To a large extent the performance of a CP system is dependent on the skill and experience of the corrosion specialist. As the underground infrastructure becomes more complex these traditional approaches may become less reliable. In an increasingly complex underground infrastructure, stray currents from other sources (such as parallel or crossing pipelines, industrial plants, or electric rail transit facilities) can come into contact with the underground steel structures.

 

(1,222KB) Applications of Boundary Elements in corrosion engineering Top
R.A. Adey, C.A. Brebbia, S.M. Niku

In recent years there has been a growing interest in the prediction of the behaviour of engineering problems involving galvanic effects. This class of problem includes galvanic corrosion, cathodic protection methods and the inverse problem of electro- deposition commonly used in manufacturing. This article will concern how a computer software system based on boundary elements can be used to accurately simulate this class of problem.

 

(729KB) Computer aided design of cathodic protection systems Top
R.A. Adey, S.M. Niku, C.A. Brebbia, J Finnegan

The design of cathodic protection systems has , like many engineering specialties, developed as an art where the corrosion engineer uses his skill and experience to produce a satisfactory design. The simple formulae which are used as part of the design process have been used skilfully but the whole scheme has been usually supported by high factors of safety. With the development of complex marine structures associated with the energy industry researchers became interested in more accurate methods of predicting the behaviour of cathodic protection systems.

 

(58KB) Corrosion basics and computer modelling Top
V.G. DeGiorgi

Corrosion is the destruction of material resulting from exposure and interaction with the environment. While common usage typically associates corrosion with metals, the destruction of non-metallic materials as a result of exposure to the environment can be considered corrosion; the disintegration of plastics when exposed to sunlight and the rotting of wood are examples of non-metallic corrosion. However, the concern of this chapter is corrosion of metals, especially electrochemical corrosion, and the ability to use computer modeling techniques to predict corrosion.

 

(313KB) Analysis of stray current corrosion problems using boundary element method Top
J. Trevelyan and H.P. Hack

Today’s offshore and ocean going structures and buried structures are fitted with systems which work to inhibit the rate at which the structure corrodes in the aggressive marine or soil environment. These operate by setting up an electrostatic field in the water surrounding the structure which causes a desired voltage and current density distribution over its surface area. These cathodic protection (CP) systems are carefully designed to offer the structure a uniform protection over its surface with the most economical use of anodes.

 

(165KB) Computer prediction of stray current corrosion Top
G.E. Strong, R.A. Adey, R.S. Rudas

The likelihood of CP interference on steel structures located in proximity to large cathodically protected chemical storage tanks was evaluated using one of the latest computer modelling techniques. Application of the Boundary Element Analysis System (BEASY) allowed CP interference to be assessed in terms of current density, which is directly proportional to the corrosion rate, rather than having to use the qualitative approach of measuring the potential shift of the soil. Furthermore, the computer modelling approach enables results to be obtained at the design stage, allowing CP systems to be optimised so that interference is minimised.

 

(964KB) A 'CAD' system for the analysis and design of cathodic protection systems Top
S.M. Niku, R.A. Adey, Chapter 13, PLANT CORROSION: Prediction of
Materials Performance, Ed, J.E. Strutt, J.R. Nicolls, Institution of Corrosion Science and Technology.


The accurate analysis of the Cathodic Protection System without the aid of computerized techniques is an impossible task due to the complexity of the geometry and environmental conditions which are typical characteristics of most practical problems. The design based on the traditional scheme involves only the overall current requirement. It does not consider geometry details or polarization on the surface of the structure, and therefore is highly dependent upon the skill and experience of the corrosion engineer.
Following the growing interest in computer modelling of corrosion problems in recent years, few computer programs have been developed.

 

(539KB) Finite resistivity and shipboard corrosion prevention system performance Top
V.G. DeGiorgi

In the computational evaluation of electrochemical corrosion systems painted surfaces are often treated as perfectly insulated. While many paint systems have a high resistance; the resistance in finite rather than infinite. In this work a range of finite resistivity values will be assigned to the painted surfaces in a boundary element model of a shipboard ICCP system. The studies performed were developed to provide an increasing understanding of the effects of finite resistivity on system performance, provide a quantitative measure of the effects of ranges of finite paint on system performance and to increase the understanding of modeling methods to issues of damage and material polarization response definitions.

 

Computer Modelling at NACE - Corrosion 99 Conference

At the recent National Association of Corrosion Engineers (NACE) Conference in San Antonio, Texas, a special session was devoted to Computer Modelling in corrosion control. BEASY and three BEASY users presented papers describing applications of modelling to solve corrosion control problems. Applications included ICCP modelling of ships and boats, design of CP systems for offshore oil and gas facilities and modelling of pipelines and underground infrastructure. It was clear from the meeting that computer modelling has matured as a technology for modelling ships and marine structures and is now widely used. With the ability to perform modelling on PC's, the technology can now be used to solve a much wider range of corrosion control problems (e.g. pipelines, underground facilities).

The papers presented were:

(168KB) Computer Simulation as an Aid to Corrosion Control and Reduction: Top
Robert A Adey & Pei Yuan Hang

 

(986KB) Examination of Modeling Assumptions for Impressed Current Cathodic Protection Systems
V G DeGiorgi, A Kee, K E Lucas & E D Thomas

 

(596KB) Boundary Element Modeling of Galvanic Anode Cathodic Protection Using the Design Slope Method
D W Townley

 

(550KB) Computer Modelling of Offshore CP Systems for 15 Years: What Have We Learned?
Per Olas Gartland, Frode Bjoernaas & Harald Osvoll

 

(539KB) Virginia DeGiorgi from the Naval Research Laboratory in Washington recently published a paper discussing how paint and coatings can be represented in BEASY cathodic protection system models.

 

(884KB) The effect of protective coatings on galvanic corrosion for bolted components Top
K.S. Yeung

The increasing demands for better fuel-efficiency have led the automobile industry to use lightweight metals such as aluminum and magnesium in conjunction with conventional metals such as steel. Galvanic corrosion is the unfortunate result of this “mixed metals” usage. The automobile companies rely primarily on proving ground testing to evaluate the severity of corrosion. Such a procedure is costly and time consuming. The objective of this project is to explore the feasibility of using computer simulation to predict galvanic corrosion in automobile environments. The BEASY code has been chosen for this project.

 

(265KB) BEM application for thin electrolyte corrosion problem Top
Y.-G. Kim, Y.-C. Kim & Y.-T. Kho

BEM methods were applied for a thin electrolyte problem. Al-Z%Zn alloy thermal spray coatings are used for seawater heat exchanger made of AI-MS alloy for LNG process utility. We investigated the remaining service life of the coating. The sprayed coating was acting as a sacrificial anode. The integrity of the coating degraded with time by peeling-off and thinning. The expected life of the coating is a crucial data for maintenance scheduling. The distribution of the corrosion potential and current were calculated with BEM analysis with BEASY CP 7.0 module. The anodic behavior of the coating was changed significantly by polymer sealing over-coating and the resultant remaining service life.

 

(343KB) Design andOptimisation of cathodic protection Systems Using Computer Similation Top
Robert Adey and John Baynham

NACE’s Annual Conference, Corrosion/2000, March 2000, Orlando, Florida

The design of cathodic protection systems normally relies on a combination of experience, experimental data and heuristics. However, problems and failures of CP systems not only has an economic cost, it can also present a threat to life and the environment. This paper will describe the application of a software system designed to simulate the performance of cathodic protection systems and predict the impact of the design parameters and the environment on its performance.

 

4.1 Defence Applications

 

(461KB) Predicting the hull state from information of potential measurements of the hull Top

Damages appear on a hull of a vessel during its lifetime. In many cases the correct position of these damages are completely unknown. Its knowledge is important from mainly two points of view.

 

(55KB) Underwater Electrical Potential Top

BEASY Corrosion and CP predicts the corrosion of ships, offshore structures, storage tanks, corrosion, pipelines etc. and the effectiveness of Protection Systems. It also predicts the near and far field underwater electric potential (UEP) “signature” of ships and boats.

 

(378KB) A Computational Environment for the Optimisation of CP system Performance and Signatures Top
E. Santana Diaz, R.A. Adey, WARSHIP 2001

In this paper an integrated set of computational tools are described which predict the level of protection of a vessel, the associated electric and magnetic signatures and automatically optimisation of the anodes to achieve the desired characteristics of the vessel. The approach adopted was to couple the BEM model of the corrosion electrode kinetics and sea- water electric field with an optimisation algorithm. 

 


(323KB) Optimisation of ICCP systems to minimise electric signatures Top
E. Santana Diaz, R.A. Adey, J. Baynham,Y. H. Pei, MARELEC 2001

In this paper an approach to the automatic optimisation of the ICCP system is presented.  The objective being to design the system to minimise the electric field while at the same time provide adequate protection.  The approach adopted was to couple the BEM model of the corrosion electrode kinetics and sea water electric field with an optimisation algorithm.  A user interface has also been developed to enable modelling and optimisation tasks to be performed quickly without the necessity of detailed changes to the BEM model.

 

(232KB) Predicting corrosion related electrical and magnetic fields using BEM Top
Robert Adey, John Baynham, UDT Europe 2000

Computer models have for some years been used to predict the performance of ICCP systems on ships and boats. The objective being to achieve optimum protection of the vessel from corrosion and to predict the associated fields/signatures. However, in many cases these models have been based on simple dipole approximations. In this paper a new system is described which integrates the electric and magnetic models to provide a tool capable of accurately predicting the impact of any change in the ICCP system, surface conditions or environmental conditions on the electric and magnetic signatures.

 

4.2 Polarisation Data

 

(2,567KB) Atlas of polarization diagrams for naval materials in seawater Top
Harvey P. Hack , CARDIVNSWC-TR-61-94/44

Polarization curves were developed in seawater at low (quiescent) flow and at 2.4 m/s flow for nine structural alloys. Potentiostatically generated curves for up to 120 days are compared with potentiodynamically generated curves at four scan rates with freely corroding pre-exposures of 1 or 120 days. Smoothed curves successjidly used in computer model predictions of cathodic protection current and potential distributions are also presented.

 

4.3 Concrete

 

(314KB) Macrocell Corrosion of Steel in Concrete - Experiments and Numerical Modelling Top
S. Jaggi, H. Bohni, B. Elsener

Macrocell corrosion with a local anode and a large cathode frequently occurs in chloride indeuced corrosion of rebars in concrete and is responsible for very high local corrosion attacks and reduction in cross section of the rebars found.